温度对Ni-Al-Fe合金早期沉淀过程的影响
梁敏洁[1] 陈铮[2] 王永欣[1] 褚忠[1]
[1]西北工业大学材料科学与工程学院,陕西西安710072 [2]西北工业大学凝固技术国家重点实验室,陕西西安710072
摘 要:
采用三元微观相场动力学模型,模拟研究了973,1173,1253K时效温度下,Ni75Al15Fe10合金中γ’相的早期沉淀过程。通过对该合金原子显微形貌,长程序参数和浓度及Fe原子在不同格点占位分数随时间演化的模拟计算分析得出:随着温度的升高,Ni75Al15Fe10合金的沉淀机制由等成分有序化兼失稳分解机制向非经典形核长大机制过渡;γ’相沉淀析出的孕育期变长;Fe原子在B格点的占位越来越困难,占位几率降低;合金沉淀析出的γ’相为单一Ll2结构的Ni3(AlFe)复合相。[著者文摘]
文章出处:
《稀有金属材料与工程》-2007年36卷10期 -1797-1801页
栏目信息:
分 类 号:
文献标识码:
A
文章编号:
1002-185X(2007)10-1797-05
The Temperature Influence on Early Precipitation Process of Ni-Al-Fe Alloy
Liang Minjie, Chen Zheng, Wang Yongxin, Chu Zhong (1. School of Material Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China) (2. State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China)
Abstract:
A ternary microscopic phase-field kinetic model was used to investigate the early γ' precipitation process of Ni75Al15Fe10 alloy by simulating the evolution of the atomic morphology, calculating long-range order parameters and concentration, and characterizing the curve of site occupation of Fe atoms at different lattice sites in the γ' phase at annealed temperatures 973, 1173, 1253 K. The results show, while the temperature increasing, γ' precipitation mechanism of Ni75Al15Fe10 alloy is transformed from the congruent ordering and spinodal decomposition to non-classic nucleation and growth; the incubation period of the γ' phase is prolonged; Fe atoms more and more difficultly occupy the B-site (the corner site of fee) and the occupation probability gradually decreases. The precipitated ),' phase (Ll2 structure) is a kind of the complex Ni3(Al1-xFex) single-phase[著者文摘]
Key words:
ageing temperature; microscopic phase-field equation; precipitation; substitute; γ' phase
基金资助:
国家自然科学基金资助(50071084);国家“863”项目(2002AA331051);西北工业大学研究生创业种子基金(Z200714)资助

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